Open your Dreamweaver and look in the top menus. Click "Site" and choose "New Site".
In the pop-up window, choose the "Advanced" tab.
Name your site anything, like Hacking Tutorial
Local info is where your website files reside on your PC that is why it is called local.
Now Select "Remote Info" and then enter the FTP settings on the right hand side
Enter the necessary information:
FTP Host: enter your domain name or IP address
Host directory: this field can be left blank (Windows accounts) or enter public_html/ (Linux accounts)
FTP login: enter your FTP username
FTP password: enter your FTP password
Click Test Connection to ensure Dreamweaver can connect to the server.
Click Next.
Ok now click on DONE and your project should appear in the Right Sidebar of Dreamweaver as shown below.